Reviews-The refraction and magnetic rotatory powers of some benzenoid hydrocarbons
نویسندگان
چکیده
منابع مشابه
Some Observations on the Topological Resonance Energy of Benzenoid Hydrocarbons*
Two empirical rules are formulated for the topological resonance energy (TRE) of benzenoid hydrocarbons: (a) TRE is roughly linear function of the number of Kekule structures, and (b) in a homologous series containing a linear polyacene fragment, TRE is a linear function of the length of this fragment. In certain cases, however, the TRE model leads to incorrect predictions. There exist pairs of...
متن کاملGraph-topological approach to magnetic properties of benzenoid hydrocarbons.
Application of topological properties and graph theory to benzenoid hydrocarbons allowed us to construct an effective approach interpreting ring current formation in molecules when exposed to an external magnetic field. Transformation of unexcited canonical structures for molecules of 34 benzenoid hydrocarbons into circuit structures and then to directed circuit structures allowed us to define ...
متن کاملEstrada Index of Benzenoid Hydrocarbons
A structure-descriptor EE, recently proposed by Estrada, is examined. If λ1, λ2, . . . ,λn are the eigenvalues of the molecular graph, then EE = n ∑ i=1 eλi . In the case of benzenoid hydrocarbons with n carbon atoms and m carbon-carbon bonds, EE is found to be accurately approximated by means of the formula a1 n cosh (√ 2m/n ) +a2, where a1 ≈ 1.098 and a2 =−0.64 are empirically determined fitt...
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Graphene has been found to be an attractive material since its discovery in 2004 and has drawn enormous interest among researchers owing to its intrinsic electronic and magnetic properties. An indefinitely large graphene sheet, if cut along the two edge directions, can generate two distinct, well-defined small graphene nanoribbons (GNRs), which may be classified into “zigzag” edge (1, transpoly...
متن کاملTopological properties of altan-benzenoid hydrocarbons
The main topological characteristics of altan-benzenoids were established. In particular, it was shown that the perimeter of Kekuléan altan-benzenoids is of size 4k , having a destablizing (anti-aromatic) energy effect, similar to (4k)-annulenes.
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ژورنال
عنوان ژورنال: The Journal of Physical Chemistry
سال: 1901
ISSN: 0092-7325,1541-5740
DOI: 10.1021/j150029a652